Synergy of phase and interface engineering of manganese difluoride enable high-efficiency potassium-ion batteries
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00499C, PaperXinru Sheng, Jiaying Liao, Zeyu Yuan, Yuhan Wang, Qiao Hu, Yichen Du, Xuefeng Wang, Xiaosi Zhou
Conversion-type materials are regarded as potential anodes for potassium-ion batteries, achieving high potassium storage capacity through conversion reactions to form K-rich compounds. However, the accompanying huge volume change often brings...
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DOI: 10.1039/D5EE00499C, PaperXinru Sheng, Jiaying Liao, Zeyu Yuan, Yuhan Wang, Qiao Hu, Yichen Du, Xuefeng Wang, Xiaosi Zhou
Conversion-type materials are regarded as potential anodes for potassium-ion batteries, achieving high potassium storage capacity through conversion reactions to form K-rich compounds. However, the accompanying huge volume change often brings...
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Compacting surface charge Layer for efficient charge transfer toward stable Zn anode
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01092F, PaperSinan Zheng, Yang Wang, Bin Luo, Kun Zhang, Leilei Sun, Zhean Bao, Guosheng Duan, Dinghao Chen, Hanwei Hu, Jingyun Huang, Zhizhen Ye
The dynamic reconstruction of electric double layers (EDLs) holds the key to stabilizing aqueous Zn metal batteries. However, the charge compatibility within EDL is destroyed by the spatiotemporal discord between...
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DOI: 10.1039/D5EE01092F, PaperSinan Zheng, Yang Wang, Bin Luo, Kun Zhang, Leilei Sun, Zhean Bao, Guosheng Duan, Dinghao Chen, Hanwei Hu, Jingyun Huang, Zhizhen Ye
The dynamic reconstruction of electric double layers (EDLs) holds the key to stabilizing aqueous Zn metal batteries. However, the charge compatibility within EDL is destroyed by the spatiotemporal discord between...
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Wearing “Body Armor” on Zinc anodes for Robust Aqueous Zinc-ion Batteries
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE05757K, PaperQunhao Wang, Xueyong Deng, Xiaolin Xue, Jian Zhang, Jiangqi Zhao, Zengyan Sui, Yuefei Zou, Longbo Luo, Wei Zhang, Xiangyang Liu, Canhui Lu
Rechargeable aqueous zinc batteries (ZIBs) are a promising device for sustainable energy storage, yet their application is hindered by uncontrollable Zn dendrite growth and parasitic reactions. Herein, a flexible membrane...
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DOI: 10.1039/D4EE05757K, PaperQunhao Wang, Xueyong Deng, Xiaolin Xue, Jian Zhang, Jiangqi Zhao, Zengyan Sui, Yuefei Zou, Longbo Luo, Wei Zhang, Xiangyang Liu, Canhui Lu
Rechargeable aqueous zinc batteries (ZIBs) are a promising device for sustainable energy storage, yet their application is hindered by uncontrollable Zn dendrite growth and parasitic reactions. Herein, a flexible membrane...
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Single Ion Conductive “Plasticine-Like” Solid Electrolyte Combined with Modulated D-Band Center of Interfacial Zinc Atoms for Highly Reversible Zinc Metal Anode
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00737B, PaperKang Yan, Yongbo Fan, Xueya Yang, Xinyu Wang, Shengmei Chen, Weijia Wang, Mingchang Zhang, Huiqing Fan, Longtao Ma
Highly concentrated salts, like 30 m ZnCl₂, can reduce free water molecules in aqueous electrolytes but also increase acidity, causing severe acid-catalyzed corrosion of the Zn anode, current collector, and...
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DOI: 10.1039/D5EE00737B, PaperKang Yan, Yongbo Fan, Xueya Yang, Xinyu Wang, Shengmei Chen, Weijia Wang, Mingchang Zhang, Huiqing Fan, Longtao Ma
Highly concentrated salts, like 30 m ZnCl₂, can reduce free water molecules in aqueous electrolytes but also increase acidity, causing severe acid-catalyzed corrosion of the Zn anode, current collector, and...
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Achieving 20% Efficiency for Binary Organic Solar Cells with Suppressed Non-radiative Recombination via Triphenylamine Halides†
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01165E, PaperJunjie Zhang, Xiaopeng Duan, Xiaoming Li, Guangkuo Dai, Jiawei Deng, Xunchang Wang, Jiawei Qiao, Hanzhi Wu, Liming Liu, Haodong Huang, Sha Liu, Jun Yan, Huotian Zhang, Xiao-Tao Hao, Renqiang Yang, Feng Gao, Yanming Sun
Minimizing energy loss has been identified as an effective approach to achieve further efficiency breakthroughs in organic solar cells (OSCs), and the main loss channel can be attributed to non-radiative...
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DOI: 10.1039/D5EE01165E, PaperJunjie Zhang, Xiaopeng Duan, Xiaoming Li, Guangkuo Dai, Jiawei Deng, Xunchang Wang, Jiawei Qiao, Hanzhi Wu, Liming Liu, Haodong Huang, Sha Liu, Jun Yan, Huotian Zhang, Xiao-Tao Hao, Renqiang Yang, Feng Gao, Yanming Sun
Minimizing energy loss has been identified as an effective approach to achieve further efficiency breakthroughs in organic solar cells (OSCs), and the main loss channel can be attributed to non-radiative...
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Amorphous Indium-Zinc Oxide Layer with Transport and Protective Dual-Function for High-Efficiency Semitransparent and Tandem Sb2(S,Se)3 Solar Cells
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE04699D, PaperJunjie Yang, Jianyu Li, Yuehao Gu, Rongfeng Tang, Lei Huang, Zhiyuan Cai, Bo Che, Qi Zhao, Shuwei Sheng, Hong Wang, Changfei Zhu, Tao Chen
Environmentally friendly Sb2(S,Se)3 with excellent optoelectronic properties is considered to be a promising light-harvesting material, which can be applied to highly efficient semitransparent solar cells when well coupled with a...
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DOI: 10.1039/D4EE04699D, PaperJunjie Yang, Jianyu Li, Yuehao Gu, Rongfeng Tang, Lei Huang, Zhiyuan Cai, Bo Che, Qi Zhao, Shuwei Sheng, Hong Wang, Changfei Zhu, Tao Chen
Environmentally friendly Sb2(S,Se)3 with excellent optoelectronic properties is considered to be a promising light-harvesting material, which can be applied to highly efficient semitransparent solar cells when well coupled with a...
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Dielectric Constant Engineering of Nonfullerene Acceptors Enables a Record Fill Factor of 83.58% and a High Efficiency of 20.80% in Organic Solar Cells
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00101C, PaperJunwei Dong, Yinfeng Li, Chentong Liao, Xiaopeng Xu, Liyang Yu, Ruipeng Li, Qiang Peng
Organic solar cells (OSCs) have shown promise with power conversion efficiencies (PCEs) exceeding 20%, but their performance still lags behind silicon-based and hybrid perovskite solar cells. A critical limitation is...
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DOI: 10.1039/D5EE00101C, PaperJunwei Dong, Yinfeng Li, Chentong Liao, Xiaopeng Xu, Liyang Yu, Ruipeng Li, Qiang Peng
Organic solar cells (OSCs) have shown promise with power conversion efficiencies (PCEs) exceeding 20%, but their performance still lags behind silicon-based and hybrid perovskite solar cells. A critical limitation is...
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Importance of hydrogen oxidation reaction current in quantifying hydrogen crossover in PEM water electrolyzers at high differential pressure
Energy Environ. Sci., 2025, Advance Article
DOI: 10.1039/D5EE00048C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ramchandra Gawas, Douglas I. Kushner, Xiong Peng, Rangachary Mukundan
This work employs online gas chromatography and hydrogen oxidation current measurements for accurate quantification of the hydrogen crossover rates in proton exchange membrane water electrolyzers operating at high differential pressure.
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DOI: 10.1039/D5EE00048C, Communication Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Ramchandra Gawas, Douglas I. Kushner, Xiong Peng, Rangachary Mukundan
This work employs online gas chromatography and hydrogen oxidation current measurements for accurate quantification of the hydrogen crossover rates in proton exchange membrane water electrolyzers operating at high differential pressure.
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Ballistic ion transport through hierarchically-ordered-structure polymer binder
Energy Environ. Sci., 2025, Advance Article
DOI: 10.1039/D4EE06071G, PaperDefu Li, Chen Fang, Santosh Thapa, Hadas Sternlicht, Gi-Hyeok Lee, Faiz Ahmed, Xiuyu Jin, Qiusu Miao, Raynald Giovine, Wanli Yang, Andrew Minor, Yang-Tse Cheng, Gao Liu
Achieving ballistic ion transport in a mixed electronic-ionic conductive polymer, its hierarchically ordered structure (HOS) facilitates ion diffusion and results in solid-state Li+ conductivity in the range of 10−4 to 10−3 S cm−1 from −20 to 70 °C.
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DOI: 10.1039/D4EE06071G, PaperDefu Li, Chen Fang, Santosh Thapa, Hadas Sternlicht, Gi-Hyeok Lee, Faiz Ahmed, Xiuyu Jin, Qiusu Miao, Raynald Giovine, Wanli Yang, Andrew Minor, Yang-Tse Cheng, Gao Liu
Achieving ballistic ion transport in a mixed electronic-ionic conductive polymer, its hierarchically ordered structure (HOS) facilitates ion diffusion and results in solid-state Li+ conductivity in the range of 10−4 to 10−3 S cm−1 from −20 to 70 °C.
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Reviving ether-based electrolytes for sodium-ion batteries
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00725A, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fangyuan Cheng, Jun Hu, Wen Zhang, Peng Yu, Xueliang Sun, Jian Peng, Baiyu Guo
The development of ether-based electrolytes has significant challenges, primarily caused by the irreversible co-intercalation of ether and Li+ into commercial graphite, which excluded ether from use in commercial lithium-ion batteries...
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DOI: 10.1039/D5EE00725A, Review Article Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Fangyuan Cheng, Jun Hu, Wen Zhang, Peng Yu, Xueliang Sun, Jian Peng, Baiyu Guo
The development of ether-based electrolytes has significant challenges, primarily caused by the irreversible co-intercalation of ether and Li+ into commercial graphite, which excluded ether from use in commercial lithium-ion batteries...
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Bio-inspired hormonic electrolyte: negative feedback for ultra-stable zinc anodes
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01058F, CommunicationFan Bu, Shaofei La, Wenbo Zhao, Yifan Deng, Yong Gao, Jizhang Jiang, Qinghe Cao, Jipeng Chen, Pei Song Chee, Salah A. Makhlouf, Cao Guan
Zn-based batteries have been considered as promising alternatives for Li-ion batteries, in terms of high safety, low cost and rich natural resources. Unfortunately, their practical application is greatly limited by...
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DOI: 10.1039/D5EE01058F, CommunicationFan Bu, Shaofei La, Wenbo Zhao, Yifan Deng, Yong Gao, Jizhang Jiang, Qinghe Cao, Jipeng Chen, Pei Song Chee, Salah A. Makhlouf, Cao Guan
Zn-based batteries have been considered as promising alternatives for Li-ion batteries, in terms of high safety, low cost and rich natural resources. Unfortunately, their practical application is greatly limited by...
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Bithiophene Imide-Based Polymer Donor for Alloy-like Ternary Organic Solar Cells with Over 20.5% Efficiency and Enhanced Stability
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00812C, PaperChangjing Xu, Jie Yang, Sergio Gámez-Valenzuela, Jin-Woo Lee, Jiaxu Che, Peng Chen, Guodong Zhang, Hu Dingqin, Yufei Wang, Jichen Lv, Zhicheng Zhong, Xihan Chen, Guangye Zhang, Fuwen Zhao, Bumjoon Kim, Xugang Guo, Bin Liu
Ternary organic solar cells (TOSCs) based on dual polymer donors offer enhanced absorption and stability by broadening spectral coverage and refining phase morphology. However, the inherent chain entanglement of dual...
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DOI: 10.1039/D5EE00812C, PaperChangjing Xu, Jie Yang, Sergio Gámez-Valenzuela, Jin-Woo Lee, Jiaxu Che, Peng Chen, Guodong Zhang, Hu Dingqin, Yufei Wang, Jichen Lv, Zhicheng Zhong, Xihan Chen, Guangye Zhang, Fuwen Zhao, Bumjoon Kim, Xugang Guo, Bin Liu
Ternary organic solar cells (TOSCs) based on dual polymer donors offer enhanced absorption and stability by broadening spectral coverage and refining phase morphology. However, the inherent chain entanglement of dual...
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Interfacial hydrogen bond modulation of dynamic catalysts for nitrate electroreduction to ammonia
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00597C, PaperYuchi Wan, Yixiang Tang, Yinze Zuo, Kaian Sun, Zewen Zhuang, Yun Zheng, Wei Yan, Jiujun Zhang, Ruitao Lv
Electrocatalytic nitrate reduction (NO3−RR) shows potentials in clean NH3 synthesis and industrial effluent disposal, turning waste into treasure. However, the catalyst reconstruction mechanism is still ambiguous, and the influence of...
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DOI: 10.1039/D5EE00597C, PaperYuchi Wan, Yixiang Tang, Yinze Zuo, Kaian Sun, Zewen Zhuang, Yun Zheng, Wei Yan, Jiujun Zhang, Ruitao Lv
Electrocatalytic nitrate reduction (NO3−RR) shows potentials in clean NH3 synthesis and industrial effluent disposal, turning waste into treasure. However, the catalyst reconstruction mechanism is still ambiguous, and the influence of...
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A Universal Surface Fixed Charge Reconstruction Strategy to Minimize Contact Loss of Wide Bandgap Perovskite Photovoltaics
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE05855K, PaperYaxiong Guo, Fang Yao, Yunchen Zhang, Guoyi Chen, Shengjie Du, Zhixi Yu, Hai Zhou, Weijun Ke, Chun Li, Guojia Fang
It is widely accepted that non-radiative recombination losses in the wide-bandgap (WBG) subcell dominate carrier recombination processes in perovskite tandem photovoltaics. We demonstrate that healing the perovskite top-surface with an...
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DOI: 10.1039/D4EE05855K, PaperYaxiong Guo, Fang Yao, Yunchen Zhang, Guoyi Chen, Shengjie Du, Zhixi Yu, Hai Zhou, Weijun Ke, Chun Li, Guojia Fang
It is widely accepted that non-radiative recombination losses in the wide-bandgap (WBG) subcell dominate carrier recombination processes in perovskite tandem photovoltaics. We demonstrate that healing the perovskite top-surface with an...
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Photoelectrochemical comproportionation of pre-treated PET plastics and CO2 to formate
Energy Environ. Sci., 2025, Advance Article
DOI: 10.1039/D5EE00689A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yongpeng Liu, Celine Wing See Yeung, Erwin Reisner
An organic–inorganic photoelectrochemical (PEC) tandem device for converting polyethylene terephthalate (PET) plastics and carbon dioxide (CO2) to formate under simulated solar irradiation.
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DOI: 10.1039/D5EE00689A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yongpeng Liu, Celine Wing See Yeung, Erwin Reisner
An organic–inorganic photoelectrochemical (PEC) tandem device for converting polyethylene terephthalate (PET) plastics and carbon dioxide (CO2) to formate under simulated solar irradiation.
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Deciphering the Interplay between Tin Vacancies and Free Carriers in the Ion Transport of Tin-Based Perovskites
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00632E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Huerta Hernandez, Luis Lanzetta, Anna M. Kotowska, Ilhan Yavuz, Nikhil Kalasariya, Badri Vishal, Martí Gibert-Roca, Matthew Piggott, David J Scurr, Stefaan De Wolf, Martin Stolterfoht, Derya Baran
Mixed ionic-electronic conduction is a prevalent phenomenon in metal halide perovskites, having a critical impact in multiple optoelectronic applications. In Sn-based halide perovskites, their higher hole density ([p]) owing to...
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DOI: 10.1039/D5EE00632E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Huerta Hernandez, Luis Lanzetta, Anna M. Kotowska, Ilhan Yavuz, Nikhil Kalasariya, Badri Vishal, Martí Gibert-Roca, Matthew Piggott, David J Scurr, Stefaan De Wolf, Martin Stolterfoht, Derya Baran
Mixed ionic-electronic conduction is a prevalent phenomenon in metal halide perovskites, having a critical impact in multiple optoelectronic applications. In Sn-based halide perovskites, their higher hole density ([p]) owing to...
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Thermoresponsive solid electrolyte interphase enables safe lithium-sulfur batteries with high energy density
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00412H, PaperFeng Jiang, Yun-Fei Du, Jia-Xin Guo, Nai-Lu Shen, Zi-Xian Chen, Mei Geng, Dongsheng Ren, Bo-Quan Li, Xue-Qiang Zhang, Tao Wang, Yuan Ma, Yiren Zhong, Jiarui He, Zhi Zhu, Faxing Wang, Jia-Qi Huang, Xin-Bing Cheng, Yuping Wu
The high-activity lithium metal anode limits the practical application of lithium-sulfur batteries in terms of both electrochemical performance and thermal safety. Solid electrolyte interphase (SEI) as a physical barrier between...
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DOI: 10.1039/D5EE00412H, PaperFeng Jiang, Yun-Fei Du, Jia-Xin Guo, Nai-Lu Shen, Zi-Xian Chen, Mei Geng, Dongsheng Ren, Bo-Quan Li, Xue-Qiang Zhang, Tao Wang, Yuan Ma, Yiren Zhong, Jiarui He, Zhi Zhu, Faxing Wang, Jia-Qi Huang, Xin-Bing Cheng, Yuping Wu
The high-activity lithium metal anode limits the practical application of lithium-sulfur batteries in terms of both electrochemical performance and thermal safety. Solid electrolyte interphase (SEI) as a physical barrier between...
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Cross-linked nanoflower network and Se-doping enabling sulfur rich SPAN towards lithium‒sulfur batteries beyond 600 Wh kg‒1
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00500K, PaperQiang Wu, Yuanke Wu, Hui Yan, Wei Zhong, Mingsheng Qin, Haolin Zhu, Shijie Cheng, Jia Xie
Sulfurized polyacrylonitrile (SPAN) is one of the most promising cathodes for high-energy-density lithium‒sulfur batteries since its distinctive organic skeleton and covalent sulfur storage mechanism effectively prevent polysulfide dissolution and mitigate...
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DOI: 10.1039/D5EE00500K, PaperQiang Wu, Yuanke Wu, Hui Yan, Wei Zhong, Mingsheng Qin, Haolin Zhu, Shijie Cheng, Jia Xie
Sulfurized polyacrylonitrile (SPAN) is one of the most promising cathodes for high-energy-density lithium‒sulfur batteries since its distinctive organic skeleton and covalent sulfur storage mechanism effectively prevent polysulfide dissolution and mitigate...
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Galvanic Corrosion Underlies Coulombic Efficiency Differences in High-Performing Lithium Metal Battery Electrolytes
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00071H, PaperSolomon T. Oyakhire, Sang Cheol Kim, Wenbo Zhang, Sanzeeda Baig Shuchi, Yi Cui, Stacey Bent
Current guidelines for electrolyte engineering in lithium metal batteries are based on design metrics such as lithium morphology, electrolyte transport properties, solid electrolyte interphase (SEI) characteristics, and lithium-electrolyte reactivity. In...
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DOI: 10.1039/D5EE00071H, PaperSolomon T. Oyakhire, Sang Cheol Kim, Wenbo Zhang, Sanzeeda Baig Shuchi, Yi Cui, Stacey Bent
Current guidelines for electrolyte engineering in lithium metal batteries are based on design metrics such as lithium morphology, electrolyte transport properties, solid electrolyte interphase (SEI) characteristics, and lithium-electrolyte reactivity. In...
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Fluorine-Free Electrolytes in Batteries: Principles, Strategies, and Advances
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE04820B, Review ArticleBoligarla Vinay, Yosef Nikodimos, Tripti Agnihotri, Shadab Ali Ahmed, Teklay Mezgebe Hagos, Rehbar Hasan, Elango Balaji Tamilarasan, Wei-Nien Su, Bing Joe Hwang
Electrolytes play a pivotal role in battery technologies, influencing performance and safety. However, electrolytes containing fluorine present adverse environmental risks due to their high greenhouse gas emissions and caution of...
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DOI: 10.1039/D4EE04820B, Review ArticleBoligarla Vinay, Yosef Nikodimos, Tripti Agnihotri, Shadab Ali Ahmed, Teklay Mezgebe Hagos, Rehbar Hasan, Elango Balaji Tamilarasan, Wei-Nien Su, Bing Joe Hwang
Electrolytes play a pivotal role in battery technologies, influencing performance and safety. However, electrolytes containing fluorine present adverse environmental risks due to their high greenhouse gas emissions and caution of...
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