Bio-inspired hormonic electrolyte: negative feedback for ultra-stable zinc anodes
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01058F, CommunicationFan Bu, Shaofei La, Wenbo Zhao, Yifan Deng, Yong Gao, Jizhang Jiang, Qinghe Cao, Jipeng Chen, Pei Song Chee, Salah A. Makhlouf, Cao Guan
Zn-based batteries have been considered as promising alternatives for Li-ion batteries, in terms of high safety, low cost and rich natural resources. Unfortunately, their practical application is greatly limited by...
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DOI: 10.1039/D5EE01058F, CommunicationFan Bu, Shaofei La, Wenbo Zhao, Yifan Deng, Yong Gao, Jizhang Jiang, Qinghe Cao, Jipeng Chen, Pei Song Chee, Salah A. Makhlouf, Cao Guan
Zn-based batteries have been considered as promising alternatives for Li-ion batteries, in terms of high safety, low cost and rich natural resources. Unfortunately, their practical application is greatly limited by...
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Bithiophene Imide-Based Polymer Donor for Alloy-like Ternary Organic Solar Cells with Over 20.5% Efficiency and Enhanced Stability
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00812C, PaperChangjing Xu, Jie Yang, Sergio Gámez-Valenzuela, Jin-Woo Lee, Jiaxu Che, Peng Chen, Guodong Zhang, Hu Dingqin, Yufei Wang, Jichen Lv, Zhicheng Zhong, Xihan Chen, Guangye Zhang, Fuwen Zhao, Bumjoon Kim, Xugang Guo, Bin Liu
Ternary organic solar cells (TOSCs) based on dual polymer donors offer enhanced absorption and stability by broadening spectral coverage and refining phase morphology. However, the inherent chain entanglement of dual...
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DOI: 10.1039/D5EE00812C, PaperChangjing Xu, Jie Yang, Sergio Gámez-Valenzuela, Jin-Woo Lee, Jiaxu Che, Peng Chen, Guodong Zhang, Hu Dingqin, Yufei Wang, Jichen Lv, Zhicheng Zhong, Xihan Chen, Guangye Zhang, Fuwen Zhao, Bumjoon Kim, Xugang Guo, Bin Liu
Ternary organic solar cells (TOSCs) based on dual polymer donors offer enhanced absorption and stability by broadening spectral coverage and refining phase morphology. However, the inherent chain entanglement of dual...
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Interfacial hydrogen bond modulation of dynamic catalysts for nitrate electroreduction to ammonia
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00597C, PaperYuchi Wan, Yixiang Tang, Yinze Zuo, Kaian Sun, Zewen Zhuang, Yun Zheng, Wei Yan, Jiujun Zhang, Ruitao Lv
Electrocatalytic nitrate reduction (NO3−RR) shows potentials in clean NH3 synthesis and industrial effluent disposal, turning waste into treasure. However, the catalyst reconstruction mechanism is still ambiguous, and the influence of...
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DOI: 10.1039/D5EE00597C, PaperYuchi Wan, Yixiang Tang, Yinze Zuo, Kaian Sun, Zewen Zhuang, Yun Zheng, Wei Yan, Jiujun Zhang, Ruitao Lv
Electrocatalytic nitrate reduction (NO3−RR) shows potentials in clean NH3 synthesis and industrial effluent disposal, turning waste into treasure. However, the catalyst reconstruction mechanism is still ambiguous, and the influence of...
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A Universal Surface Fixed Charge Reconstruction Strategy to Minimize Contact Loss of Wide Bandgap Perovskite Photovoltaics
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE05855K, PaperYaxiong Guo, Fang Yao, Yunchen Zhang, Guoyi Chen, Shengjie Du, Zhixi Yu, Hai Zhou, Weijun Ke, Chun Li, Guojia Fang
It is widely accepted that non-radiative recombination losses in the wide-bandgap (WBG) subcell dominate carrier recombination processes in perovskite tandem photovoltaics. We demonstrate that healing the perovskite top-surface with an...
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DOI: 10.1039/D4EE05855K, PaperYaxiong Guo, Fang Yao, Yunchen Zhang, Guoyi Chen, Shengjie Du, Zhixi Yu, Hai Zhou, Weijun Ke, Chun Li, Guojia Fang
It is widely accepted that non-radiative recombination losses in the wide-bandgap (WBG) subcell dominate carrier recombination processes in perovskite tandem photovoltaics. We demonstrate that healing the perovskite top-surface with an...
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Photoelectrochemical comproportionation of pre-treated PET plastics and CO2 to formate
Energy Environ. Sci., 2025, Advance Article
DOI: 10.1039/D5EE00689A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yongpeng Liu, Celine Wing See Yeung, Erwin Reisner
An organic–inorganic photoelectrochemical (PEC) tandem device for converting polyethylene terephthalate (PET) plastics and carbon dioxide (CO2) to formate under simulated solar irradiation.
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DOI: 10.1039/D5EE00689A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Yongpeng Liu, Celine Wing See Yeung, Erwin Reisner
An organic–inorganic photoelectrochemical (PEC) tandem device for converting polyethylene terephthalate (PET) plastics and carbon dioxide (CO2) to formate under simulated solar irradiation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Deciphering the Interplay between Tin Vacancies and Free Carriers in the Ion Transport of Tin-Based Perovskites
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00632E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Huerta Hernandez, Luis Lanzetta, Anna M. Kotowska, Ilhan Yavuz, Nikhil Kalasariya, Badri Vishal, Martí Gibert-Roca, Matthew Piggott, David J Scurr, Stefaan De Wolf, Martin Stolterfoht, Derya Baran
Mixed ionic-electronic conduction is a prevalent phenomenon in metal halide perovskites, having a critical impact in multiple optoelectronic applications. In Sn-based halide perovskites, their higher hole density ([p]) owing to...
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DOI: 10.1039/D5EE00632E, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Luis Huerta Hernandez, Luis Lanzetta, Anna M. Kotowska, Ilhan Yavuz, Nikhil Kalasariya, Badri Vishal, Martí Gibert-Roca, Matthew Piggott, David J Scurr, Stefaan De Wolf, Martin Stolterfoht, Derya Baran
Mixed ionic-electronic conduction is a prevalent phenomenon in metal halide perovskites, having a critical impact in multiple optoelectronic applications. In Sn-based halide perovskites, their higher hole density ([p]) owing to...
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Thermoresponsive solid electrolyte interphase enables safe lithium-sulfur batteries with high energy density
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00412H, PaperFeng Jiang, Yun-Fei Du, Jia-Xin Guo, Nai-Lu Shen, Zi-Xian Chen, Mei Geng, Dongsheng Ren, Bo-Quan Li, Xue-Qiang Zhang, Tao Wang, Yuan Ma, Yiren Zhong, Jiarui He, Zhi Zhu, Faxing Wang, Jia-Qi Huang, Xin-Bing Cheng, Yuping Wu
The high-activity lithium metal anode limits the practical application of lithium-sulfur batteries in terms of both electrochemical performance and thermal safety. Solid electrolyte interphase (SEI) as a physical barrier between...
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DOI: 10.1039/D5EE00412H, PaperFeng Jiang, Yun-Fei Du, Jia-Xin Guo, Nai-Lu Shen, Zi-Xian Chen, Mei Geng, Dongsheng Ren, Bo-Quan Li, Xue-Qiang Zhang, Tao Wang, Yuan Ma, Yiren Zhong, Jiarui He, Zhi Zhu, Faxing Wang, Jia-Qi Huang, Xin-Bing Cheng, Yuping Wu
The high-activity lithium metal anode limits the practical application of lithium-sulfur batteries in terms of both electrochemical performance and thermal safety. Solid electrolyte interphase (SEI) as a physical barrier between...
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Cross-linked nanoflower network and Se-doping enabling sulfur rich SPAN towards lithium‒sulfur batteries beyond 600 Wh kg‒1
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00500K, PaperQiang Wu, Yuanke Wu, Hui Yan, Wei Zhong, Mingsheng Qin, Haolin Zhu, Shijie Cheng, Jia Xie
Sulfurized polyacrylonitrile (SPAN) is one of the most promising cathodes for high-energy-density lithium‒sulfur batteries since its distinctive organic skeleton and covalent sulfur storage mechanism effectively prevent polysulfide dissolution and mitigate...
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DOI: 10.1039/D5EE00500K, PaperQiang Wu, Yuanke Wu, Hui Yan, Wei Zhong, Mingsheng Qin, Haolin Zhu, Shijie Cheng, Jia Xie
Sulfurized polyacrylonitrile (SPAN) is one of the most promising cathodes for high-energy-density lithium‒sulfur batteries since its distinctive organic skeleton and covalent sulfur storage mechanism effectively prevent polysulfide dissolution and mitigate...
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Galvanic Corrosion Underlies Coulombic Efficiency Differences in High-Performing Lithium Metal Battery Electrolytes
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00071H, PaperSolomon T. Oyakhire, Sang Cheol Kim, Wenbo Zhang, Sanzeeda Baig Shuchi, Yi Cui, Stacey Bent
Current guidelines for electrolyte engineering in lithium metal batteries are based on design metrics such as lithium morphology, electrolyte transport properties, solid electrolyte interphase (SEI) characteristics, and lithium-electrolyte reactivity. In...
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DOI: 10.1039/D5EE00071H, PaperSolomon T. Oyakhire, Sang Cheol Kim, Wenbo Zhang, Sanzeeda Baig Shuchi, Yi Cui, Stacey Bent
Current guidelines for electrolyte engineering in lithium metal batteries are based on design metrics such as lithium morphology, electrolyte transport properties, solid electrolyte interphase (SEI) characteristics, and lithium-electrolyte reactivity. In...
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Fluorine-Free Electrolytes in Batteries: Principles, Strategies, and Advances
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE04820B, Review ArticleBoligarla Vinay, Yosef Nikodimos, Tripti Agnihotri, Shadab Ali Ahmed, Teklay Mezgebe Hagos, Rehbar Hasan, Elango Balaji Tamilarasan, Wei-Nien Su, Bing Joe Hwang
Electrolytes play a pivotal role in battery technologies, influencing performance and safety. However, electrolytes containing fluorine present adverse environmental risks due to their high greenhouse gas emissions and caution of...
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DOI: 10.1039/D4EE04820B, Review ArticleBoligarla Vinay, Yosef Nikodimos, Tripti Agnihotri, Shadab Ali Ahmed, Teklay Mezgebe Hagos, Rehbar Hasan, Elango Balaji Tamilarasan, Wei-Nien Su, Bing Joe Hwang
Electrolytes play a pivotal role in battery technologies, influencing performance and safety. However, electrolytes containing fluorine present adverse environmental risks due to their high greenhouse gas emissions and caution of...
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High-Iodine-Loading Quasi-Solid-State Zinc-Iodine Batteries Enabled by a Continuous Ion-Transport Network
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01170A, PaperXin Yang, Minghao Xie, Zhijie Yan, Hang Ruan, Chunpeng Yang, Zaiping Guo, Zi-Jian Zheng
Zinc-iodine (Zn–I₂) batteries are promising candidates for next-generation large-scale energy storage systems due to their inherent safety, environmental sustainability, and potential cost-effectiveness compared to lithium-ion batteries. Their applications, however, have...
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DOI: 10.1039/D5EE01170A, PaperXin Yang, Minghao Xie, Zhijie Yan, Hang Ruan, Chunpeng Yang, Zaiping Guo, Zi-Jian Zheng
Zinc-iodine (Zn–I₂) batteries are promising candidates for next-generation large-scale energy storage systems due to their inherent safety, environmental sustainability, and potential cost-effectiveness compared to lithium-ion batteries. Their applications, however, have...
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Recent Advances in Perovskite Air Electrode Materials for Protonic Solid Oxide Electrochemical Cells
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00983A, Review ArticleCancan Peng, xu han, Sebete S Mabaleha, Philip Kwong, Yao Zheng, Xiaoyong Xu
Intermediate-temperature proton-conducting solid oxide cells (P-SOCs) have emerged as a promising technology for power generation and hydrogen production. They have gained significant attention due to their lower operating temperature, higher...
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DOI: 10.1039/D5EE00983A, Review ArticleCancan Peng, xu han, Sebete S Mabaleha, Philip Kwong, Yao Zheng, Xiaoyong Xu
Intermediate-temperature proton-conducting solid oxide cells (P-SOCs) have emerged as a promising technology for power generation and hydrogen production. They have gained significant attention due to their lower operating temperature, higher...
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The electrode-electrolyte interface of Cu via modulation excitation X-ray absorption spectroscopy
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01068C, CommunicationAngel T. Garcia-Esparza, Xiang Li, Finn Babbe, Jinkyu Lim, K. Dean Skoien, Philipp Stefan Simon, Junko Yano, Dimosthenis Sokaras
Accessing the electrode-electrolyte interface under operating conditions and capturing time-resolved kinetics challenge electrochemical studies. Copper’s interfacial oxidation dynamics remain unclear despite extensive research. Modulation excitation X-ray absorption spectroscopy (ME-XAS) probes...
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DOI: 10.1039/D5EE01068C, CommunicationAngel T. Garcia-Esparza, Xiang Li, Finn Babbe, Jinkyu Lim, K. Dean Skoien, Philipp Stefan Simon, Junko Yano, Dimosthenis Sokaras
Accessing the electrode-electrolyte interface under operating conditions and capturing time-resolved kinetics challenge electrochemical studies. Copper’s interfacial oxidation dynamics remain unclear despite extensive research. Modulation excitation X-ray absorption spectroscopy (ME-XAS) probes...
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Advanced Energy Harvesting from Low-Frequency Ocean Waves for Lithium-Ion Battery Applications
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01492A, PaperYingjin Luo, Wentao Lei, Pengfei Chen, Tao Jiang, Andeng Liu, Meidan Ye, Zijie Xu, Zhong Lin Wang, Wenxi Guo
The low root mean square (RMS) current density generated by triboelectric nanogenerators (TENGs) has significantly hindered their effectiveness in charging lithium batteries. In response, we present a universal energy storage...
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DOI: 10.1039/D5EE01492A, PaperYingjin Luo, Wentao Lei, Pengfei Chen, Tao Jiang, Andeng Liu, Meidan Ye, Zijie Xu, Zhong Lin Wang, Wenxi Guo
The low root mean square (RMS) current density generated by triboelectric nanogenerators (TENGs) has significantly hindered their effectiveness in charging lithium batteries. In response, we present a universal energy storage...
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Upcycling spent medium-Ni cathodes via novel liquified salts sourcing
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01086A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Moonsu Yoon, Jin-sung Park, Weiyin Chen, Yimeng Huang, Tao Dai, Yumin Lee, Jungmin Shin, Seungmi Lee, Yongil Kim, Dongsoo Lee, Daiha Shin, Jaephil Cho, Yanhao Dong, Ju Li
The rapid growth in lithium-ion battery technology underscores the urgent need for sustainable recycling to address the environmental and economic challenges of battery wastes. This study introduces a liquified-salts-assisted upcycling...
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DOI: 10.1039/D5EE01086A, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Moonsu Yoon, Jin-sung Park, Weiyin Chen, Yimeng Huang, Tao Dai, Yumin Lee, Jungmin Shin, Seungmi Lee, Yongil Kim, Dongsoo Lee, Daiha Shin, Jaephil Cho, Yanhao Dong, Ju Li
The rapid growth in lithium-ion battery technology underscores the urgent need for sustainable recycling to address the environmental and economic challenges of battery wastes. This study introduces a liquified-salts-assisted upcycling...
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Dynamic Cathode Interlayer for Ultralow Self-Discharge and High Iodide Utilization in Zinc-Iodine Batteries
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE05584E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Junming Kang, Jiajia Zhang, Wan Wang, Zhimin Zhai, Ganxiong Liu, Ying Ge, Lequan Wang, Chao Wang, Hongbin Lu
Aqueous zinc-iodine (Zn-I2) batteries are highly desirable for grid energy storage but subjected to polyiodide shuttling, which leads to low Coulombic efficiency (less than 98%), severe self-discharge (over 10% after...
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DOI: 10.1039/D4EE05584E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Junming Kang, Jiajia Zhang, Wan Wang, Zhimin Zhai, Ganxiong Liu, Ying Ge, Lequan Wang, Chao Wang, Hongbin Lu
Aqueous zinc-iodine (Zn-I2) batteries are highly desirable for grid energy storage but subjected to polyiodide shuttling, which leads to low Coulombic efficiency (less than 98%), severe self-discharge (over 10% after...
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Mitigating chemo-mechanical heterogeneity of Ni-rich layered cathodes through the regulated medium-range order by doping
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01180A, PaperJunfeng Luo, Gi-Hyeok Lee, Jiliang Zhang, Seongkoo Kang, Chi Liang Chen, Chung-Kai Chang, Zheng-Yao Li, Ronghua Zeng, Hong Li, Jialu Li, Ruirui Zhao, Qifeng Zheng, Yong-Mook Kang
Structural heterogeneity-induced chemo-mechanical interplay has been identified as the primary reason for the capacity degradation of high-voltage Ni-rich layered cathodes. In the current study, two dopants known to have different...
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DOI: 10.1039/D5EE01180A, PaperJunfeng Luo, Gi-Hyeok Lee, Jiliang Zhang, Seongkoo Kang, Chi Liang Chen, Chung-Kai Chang, Zheng-Yao Li, Ronghua Zeng, Hong Li, Jialu Li, Ruirui Zhao, Qifeng Zheng, Yong-Mook Kang
Structural heterogeneity-induced chemo-mechanical interplay has been identified as the primary reason for the capacity degradation of high-voltage Ni-rich layered cathodes. In the current study, two dopants known to have different...
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High-Conversion-Efficiency and Stable Six-Electron Zn-I2 Batteries Enabled by Organic Iodide/Thiazole-Linked Covalent Organic Frameworks
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00365B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenyan Du, Qi Huang, Xunwen Zheng, Yaokang Lv, Ling Miao, Ziyang Song, Lihua Gan, Mingxian Liu
Six-electron I−/I5+ redox chemistry gives a promising platform to propel high-capacity Zn-I2 batteries, but faces limited conversion efficiency and instability of IO3− species. Here we design a thiazole-linked covalent organic...
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DOI: 10.1039/D5EE00365B, Paper Open Access   This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Wenyan Du, Qi Huang, Xunwen Zheng, Yaokang Lv, Ling Miao, Ziyang Song, Lihua Gan, Mingxian Liu
Six-electron I−/I5+ redox chemistry gives a promising platform to propel high-capacity Zn-I2 batteries, but faces limited conversion efficiency and instability of IO3− species. Here we design a thiazole-linked covalent organic...
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Performance Metrics of Triboelectric Nanogenerator toward Record-High Output Energy Density
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00376H, PaperRu Guo, Hang Luo, Shaoshuai He, Xin Xia, Tingting Hou, Haoyu WANG, Chaojie Chen, Dou Zhang, Yunlong Zi
The state-of-the-art studies have promoted the output energy density of the triboelectric nanogenerator (TENG) to be 10^5 J m^-3 level, while the current major barrier lies on the breakdown discharge...
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DOI: 10.1039/D5EE00376H, PaperRu Guo, Hang Luo, Shaoshuai He, Xin Xia, Tingting Hou, Haoyu WANG, Chaojie Chen, Dou Zhang, Yunlong Zi
The state-of-the-art studies have promoted the output energy density of the triboelectric nanogenerator (TENG) to be 10^5 J m^-3 level, while the current major barrier lies on the breakdown discharge...
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Synergistically enhancing the selective adsorption for crystal planes to regulate the (002)-texture preferred Zn deposition via supramolecular host-guest units
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00763A, PaperLequan Wang, Yizhen Shao, Zhongheng Fu, Xianfu Zhang, Junming Kang, Xingxiu Yang, Zhimin Zhai, Ying Ge, Long Zhang, Yanglong Hou, Hongbin Lu
Uncontrollable dendrite growth and parasitic reactions lead to poor reversibility of zinc (Zn) anodes, which seriously hinders the commercialization of aqueous Zn metal batteries. A promising strategy to address these...
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DOI: 10.1039/D5EE00763A, PaperLequan Wang, Yizhen Shao, Zhongheng Fu, Xianfu Zhang, Junming Kang, Xingxiu Yang, Zhimin Zhai, Ying Ge, Long Zhang, Yanglong Hou, Hongbin Lu
Uncontrollable dendrite growth and parasitic reactions lead to poor reversibility of zinc (Zn) anodes, which seriously hinders the commercialization of aqueous Zn metal batteries. A promising strategy to address these...
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