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NanoManufacturing

Michael De Volder, Engineering Department - IfM
 

Tue 27 May 13:00: Computer Vision: Between Forensics and Biomedical Imaging

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 17:51
Computer Vision: Between Forensics and Biomedical Imaging

The seminar will be an interdisciplinary journey between applications of Artificial Intelligence (AI) Computer Vision based methods to the field of Forensics and Biomedical Imaging. I will first focus on AI applications for country recognition and city verification, presenting two works in which AI based models have been applied to such forensics task, with a final overview of other forensics applications such as visual sentiment analysis and detection of generated images through AI methods. Subsequently the seminar will focus on further applications of AI vision methods to the field of deep generative models for Biomedical Imaging, with a particular focus on a work on deep generative model for structural brain MRI reconstruction and interpretation.

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Wed 14 May 16:00: Profinite rigidity of Kähler groups

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 17:12
Profinite rigidity of Kähler groups

A classical problem in complex algebraic geometry is understanding the topology of closed complex submanifolds of complex projective space, so-called smooth complex projective varieties, and, more generally, of compact Kähler manifolds. Two natural topological invariants to consider are the fundamental group and its profinite completion; the latter is also known as the algebraic fundamental group. In this talk I will address the following questions: When is the fundamental group of a compact Kähler manifold uniquely determined by its profinite completion? And, when does the profinite completion even determine the homeomorphism type of the underlying manifold? In particular, I will explain positive answers to both questions in the case of a direct product of fundamental groups of closed hyperbolic Riemann surfaces. This talk is based on joint work with Hughes, Py, Spitler, Stover and Vidussi.

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Tue 13 May 14:00: Harmonic maps to the circle with higher dimensional singular set

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 16:35
Harmonic maps to the circle with higher dimensional singular set

We consider the problem of finding harmonic maps to the circle with a prescribed singular set in an arbitrary Riemannian manifold and characterise their uniqueness in terms of the “one-dimensional topology” of the ambient space. We then show how these maps can be used to define new notions of (n-2)-volume, leading to a promising approximation scheme for classical codimension 2 minimal surfaces.

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Wed 14 May 14:30: Nanoconfined Superionic Water is Molecular Superionic

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 15:50
Nanoconfined Superionic Water is Molecular Superionic

Superionic ice, where water molecules dissociate into a lattice of oxygen ions and a rapidly diffusing “gas” of protons, represents an exotic state of matter with broad implications for planetary interiors and energy applications [1,2]. Recently, a nanoconfined superionic state of water has been predicted [3,4], which exists at far milder temperatures than conventional superionic ices and at pressures similar to those created naturally in Van der Waals materials [5]. Interestingly, in sharp contrast to bulk ice, this phase is comprised of intact water molecules. This molecular superionic behaviour has possible applications in a range of electrochemical and electrocatalytic applications. However, at present, we lack the design principles necessary to design other materials with these properties.

In this talk, I will use machine learning and electronic structure simulations to establish how nanoconfined water can be both molecular and superionic. We also explore what insights this material offers for superionic states in general. Similar to bulk superionic ice and other superionic materials [6], nanoconfined water conducts via concerted chain-like proton migrations, which cause the rapid propagation of defects [7]. However, unlike other molecular phases of water, its exceptional conductivity arises from: (i) low barriers to proton transfer; and (ii) a flexible hydrogen-bonded network. We propose that these are two key characteristics of fast ionic conduction in molecular superionics. The insights obtained here establish design principles for the discovery of other molecular superionic materials, with potential applications in energy storage and beyond.

References: 1. Matusalem F et al. (2022) Plastic deformation of superionic water ices. Proc Natl Acad Sci USA119 :e2203397119. https://doi.org/10.1073/pnas.2203397119 2. Cheng B et al. (2021) Phase behaviours of superionic water at planetary conditions. Nat Phys 17(11):1228–1232. https://doi.org/10.1038/s41567-021-01334-9 3. Kapil V et al. (2022) The first-principles phase diagram of monolayer nanoconfined water. Nature 609(7927):512–516. https://doi.org/10.1038/s41586-022-05036-x 4. Ravindra P et al. (2024) Nuclear quantum effects induce superionic proton transport in nanoconfined water. arXivpreprint arXiv:2410.03272. https://arxiv.org/abs/2410.03272 5. Algara-Siller G et al. (2015) Square ice in graphene nanocapillaries. Nature 519(7544):443–445. https://doi.org/10.1038/nature14295 6. Morgan BJ (2021) Mechanistic origin of superionic lithium diffusion in anion-disordered Li₆PS₅X argyrodites. Chem Mater 33(6):2004–2018. https://doi.org/10.1021/acs.chemmater.0c03738 7. Catlow CRA (1990) Atomistic mechanisms of ionic transport in fast-ion conductors. J Chem Soc, Faraday Trans86(8):1167. https://doi.org/10.1039/FT9908601167

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Tue 13 May 14:00: BSU Seminar: "A Regression Tree Approach to Missing Data" This will be a free hybrid seminar. To register to attend virtually, please click here: https://cam-ac-uk.zoom.us/j/81415700586?pwd=7rhWD5jDWlkAq1nuMUPDJGDkhQsMCM.1

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 14:56
BSU Seminar: "A Regression Tree Approach to Missing Data"

Analysis of data with missing values is arguably the hardest problem in statistics. Statistical methods are often designed for completely observed data and are inapplicable if some values are missing. Although there are many techniques for imputation of missing values, the statistical properties of the resulting fitted models are unknown, except in special situations that require unverifiable and likely unjustifiable assumptions, such as “missing at random” (MAR) and “no unobserved confounding”.

We use a large dataset of electronic health records of Covid-19 patients and a national consumer expenditure survey to show that (1) routine imputation of missing data is inadvisable and even illogical, as missingness itself can contain useful information that imputation destroys and (2) popular imputation algorithms such as MICE are impractical when the amount of missing data is large. We also show how the GUIDE classification and regression tree method easily overcomes these difficulties. GUIDE is unique among tree algorithms in many respects, including its ability to completely avoid imputation of missing data in predictor variables and to explicitly display the effects of missing values in its decision tree diagrams. Literature on GUIDE and its accompanying software may be obtained at https://pages.stat.wisc.edu/~loh/guide.html.

This will be a free hybrid seminar. To register to attend virtually, please click here: https://cam-ac-uk.zoom.us/j/81415700586?pwd=7rhWD5jDWlkAq1nuMUPDJGDkhQsMCM.1

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Radical Scavenger-Driven Oxidation Prevention and Structural Stabilization for Efficient and Stable Tin-Based Perovskite Solar Cells

http://feeds.rsc.org/rss/ee - Wed, 07/05/2025 - 12:41
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE00735F, PaperSeungon Jung, Yunjeong Jang, Hohyun Jung, Yujin Kim, Eunbin Son, Seulgi Jeong, Yihan Zhang, Joohoon Kang, Jeong Min Baik, Jianfeng Lu, Hyesung Park
Tin (Sn)-based perovskite solar cells (PSCs) have emerged as promising alternatives to lead-based PSCs owing to their lower toxicity and desirable optoelectronic properties. However, the instability of Sn-based perovskites and...
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Reducing Energy Loss by Developing Luminescent Triphenylamine Functionalized Electron Acceptor for High Performance Organic Solar Cells

http://feeds.rsc.org/rss/ee - Wed, 07/05/2025 - 12:41
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D5EE01525A, PaperYue Chen, Xiaopeng Duan, Junjie Zhang, Zhongwei Ge, Haisheng Ma, Xiaobo Sun, Huotian Zhang, Jiaxin Gao, Xuelin Wang, Xunchang Wang, Zheng Tang, Renqiang Yang, Feng Gao, Yanming Sun
The persistent challenge of high non-radiative recombination energy loss (ΔEnr) remains a critical bottleneck in advancing the power conversion efficiency (PCE) of organic solar cells (OSCs). Herein, a fused non-fullerene...
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Closing the Carbon Cycle: Challenges and Opportunities of CO2 Electrolyser Designs in Light of Cross-Industrial CO2 Source-Sink Matching in the European Landscape

http://feeds.rsc.org/rss/ee - Wed, 07/05/2025 - 12:41
Energy Environ. Sci., 2025, Accepted Manuscript
DOI: 10.1039/D4EE06204C, Analysis Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Muhammad Tayyab, Maximiliane Dreis, Dennis Blaudszun, Kevinjeorjios Pellumbi, Urbain Nzotcha, Muhammad Qaiser Masood, Sebastian Stiessel, Henning Weinrich, Hermann Tempel, Kai junge Puring, Ruediger-A. Eichel, Ulf-Peter Apfel
The defossilisation of the chemical industry is a critical milestone in achieving climate-friendly and sustainable production routes. In this regard, CO2-electrolysis technologies have emerged as a foundational element of Carbon...
The content of this RSS Feed (c) The Royal Society of Chemistry

Conjugated Side‐Chains Optimize Giant Acceptor Compatibility with Low‐Cost Polymer Donor to Overcome the Cost‐Efficiency‐Stability Trilemma in Polymer Solar Cells

High-efficiency and stable polymer solar cells typically rely on expensive oligomeric small-molecule acceptors and high-cost polymer donors. To overcome this limitation, conjugated side chains are strategically employed to modulate and dimerize acceptors, precisely tuning their thermodynamic properties for optimal compatibility with the low-cost polymer donor PTQ10. This approach provides a viable pathway toward sustainable and renewable energy solutions.


Abstract

Polymer solar cells (PSCs) rely on blends of small-molecule acceptors (SMAs) and polymer donors, but the thermodynamic relaxation of SMAs requires an oligomeric approach to enhance operational stability. However, high-efficiency devices often depend on the expensive synthesis of oligomeric SMAs and costly polymer donors, posing a significant barrier to achieving sustainable and renewable energy. Here, the challenge is addressed through a thermodynamically derived compatibility of giant acceptors with the low-cost polymer donor PTQ10. This is achieved by strategically employing conjugated side chains to modulate and dimerize acceptors, thereby precisely tuning their thermodynamic properties to optimize compatibility. Our synthetic route avoids toxic reagents, halogenated solvents, and harsh conditions. The dimer (DYBT) incorporating an n-type linker enhances crystallinity, absorption, and intramolecular superexchange coupling compared to its p-type counterpart, and achieves a device efficiency of 19.53%. Considering efficiency, stability, and material cost, the potential cost per kilowatt for the PTQ10:DYBT device is 0.10 $ kW−1, while most systems exceed 10 $ kW−1. These findings offer valuable insights for the cost-effective oligomeric acceptors, to well pair with low-cost donors and reduce the overall material cost of the photo-active layer for sustainable and durable energy.

Natural van der Waals Canalization Lens for Non‐Destructive Nanoelectronic Circuit Imaging and Inspection

Canalization-based super-resolution imaging has been achieved based on ultralow-loss and extremely anisotropic phonon polaritons in a natural van der Waals material α-MoO3. This canalization lens exhibits the superior capability to resolve deeply subwavelength feature sizes down to 15 nm, which represents a promising solution for non-destructive nanoelectronic circuit imaging and inspection.


Abstract

Optical inspection has long served as a cornerstone non-destructive method in semiconductor wafer manufacturing, particularly for surface and defect analysis. However, conventional techniques such as dark-field scattering optics or atomic force microscopy (AFM) face significant limitations, including insufficient resolution or the inability to resolve subsurface features. Here, an approach is proposed that integrates the strengths of dark-field scattering optics and AFM by leveraging a van der Waals (vdW) canalization lens based on natural biaxial α-MoO3 crystals. This method enables ultrahigh-resolution subwavelength imaging with the ability to visualize both surface and buried structures, achieving a spatial resolution of 15 nm and grating pitch detection down to 100 nm. The underlying mechanism relies on the unique anisotropic properties of α-MoO3, where its atomic-scale unit cells and biaxial symmetry facilitate the diffraction-free propagation of both evanescent and propagating waves via a flat-band canalization regime. Unlike metamaterial-based superlenses and hyperlenses, which suffer from high plasmonic losses, fabrication imperfections, and uniaxial constraints, α-MoO3 provides robust and super-resolution imaging in multiple directions. The approach is successfully applied to achieve high-resolution inspection of buried nanoscale electronic circuits, offering unprecedented capabilities essential for next-generation semiconductor manufacturing.

Mon 02 Jun 14:00: Title to be confirmed

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 12:05
Title to be confirmed

Abstract not available

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Mon 09 Jun 14:00: Title to be confirmed

http://talks.cam.ac.uk/show/rss/5408 - Wed, 07/05/2025 - 12:04
Title to be confirmed

Abstract not available

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Latest news

We are hiring!

4 January 2021

We are seeking to hire a research assistant to work on carbon nanotube based microdevices. More information is available here: www.jobs.cam.ac.uk/job/28202/

We are Hiring!

4 January 2021

We are seeking to hire a postdoc researcher to work on the structuring of Li-ion battery electrodes. More information is available here: www.jobs.cam.ac.uk/job/28197/